SEGH Articles

In Memoriam: Willard R Chappell PhD

24 November 2017
With great sadness we have learned of the death of Willard (Bill) Chappell on October 7, 2017.

In Memoriam

Willard R Chappell PhD

With great sadness we have learned of the death of Willard (Bill) Chappell  on October 7, 2017.

Bill was Professor (subsequently Professor Emeritus) of Physics and Preventive Medicine at the University of Colorado Denver (USA). Bill joined our society in 1988 and was elected Secretary/Treasurer for 1989 through 1991. He served on the Board from 1992 to 2004 in a special position as Task Force Chairman of the SEGH Arsenic Task Force.  The work of the Task Force led to the Arsenic Exposure and Health Problems conferences  in 1993, 1995, 1998, 2000 and 2002. In addition to the  conference proceedings three books (Arsenic Exposure and Health Effects, edited by Willard Chappell, Charles Abernathy and Rebecca Calderon) were published. These publications were very well received by the international research community and influenced the setting of drinking water standards for arsenic. In 2005 Bill Chappell's efforts were recognized by the (SEGH) Julian J. Chisolm, Jr. Award for Outstanding Leadership in Environmental  Geochemistry and Health.

In his academic life Bill, in addition to his activities as an educator and researcher,  was Chairman of the State of Colorado Governors Scientific Advisory Committee in 1974-1975 and Chairman of the United State Department of Energy Oil Shale Task Force from 1978-1982.  In the academic year 1983/1984 he had a sabbatical leave in England as Academic Visitor in London University's Imperial College.

Bill's father and mother Will and Mildred preceded him in death.  Bill is survived by two brothers, Robert Bruce Chappell and John Heizer.  Bill's wife Juanita Benetin, whom he married on March 5, 1981 their two children Ginger Ferguson and her Husband, Robert Snook, and Robert Lincoln Ferguson, Jr.

Those of us who were privileged to know him  remember him not only for his active leadership in our society but also for him as a person, as good company, as fun. He was best described as a bon viveur, amply living up to the dictionary definition as a person who likes going to parties and who enjoys good food and wine. He was reputed to know the best restaurants in cities throughout the world.

Brian E Davies and Bobby G Wixson (Past Presidents)


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Latest on-line papers from the SEGH journal: Environmental Geochemistry and Health

  • Arsenic exposure and perception of health risk due to groundwater contamination in Majuli (river island), Assam, India 2019-07-19


    Island populations are rarely studied for risk of arsenic (As) poisoning. As poisoning, multimetal contamination and people’s perceptions of health risks were assessed on India’s Majuli Island, the largest inhabited river island in the world. This holistic approach illustrated the association of groundwater contamination status with consequent health risk by measuring levels of inorganic arsenic (iAs) in groundwater, borehole sediment and biological samples (hair, nails and urine). Piper and Gibbs’s plots discerned the underlying hydrogeochemical processes in the aquifer. Demographic data and qualitative factors were evaluated to assess the risks and uncertainties of exposure. The results exhibited significant enrichment of groundwater with As, Mn and Fe along with significant body burden. Maximum Hazard Index values indicated severe non-carcinogenic health impacts as well as a significantly elevated risk of cancer for both adults and children. Most (99%) of the locally affected population did not know about the adverse health impacts of metal contamination, and only 15% understood bodily ailments and health issues. Various aspects of the island environment were used to elucidate the status of contamination and future risk of disease. A projection showed adverse health outcomes rising significantly, especially among the young population of Majuli, due to overexposure to not only As but also Ba, Mn and Fe.

  • The contents of the potentially harmful elements in the arable soils of southern Poland, with the assessment of ecological and health risks: a case study 2019-07-19


    Agricultural soil samples were collected from the areas where edible plants had been cultivated in southern Poland. The PHE content decreased in proportion to the median value specified in brackets (mg/kg d.m.) as follows: Zn (192) > Pb (47.1) > Cr (19.6) > Cu (18.8) > Ni (9.91) > As (5.73) > Co (4.63) > Sb (0.85) > Tl (0.04) > Cd (0.03) > Hg (0.001) > Se (< LOQ). No PHE concentrations exceeded the permissible levels defined in the Polish law. The PHE solubility (extracted with CaCl2) in the total concentration ranged in the following order: Fe (3.3%) > Cd (2.50%) > Ni (0.75%) > Zn (0.48%) > Cu (0.19%) > Pb (0.10%) > Cr (0.03%). The soil contamination indices revealed moderate contamination with Zn, ranging from uncontaminated to moderately contaminated with Pb, and, practically, no contamination with other PHEs was identified. The ecological risk indices revealed that soils ranged from uncontaminated to slightly contaminated with Zn, Pb, As, Cu, and Ni. The PCA indicated natural sources of origin of Co, Cu, Hg, Sb, Zn, Cr, and Pb, as well as anthropogenic sources of origin of Cd, Ni, As, and Tl. The human health risk assessment (HHRA) for adults and children decreased in the following order of exposure pathways: ingestion > dermal contact > inhalation of soil particles. The total carcinogenic risk values for both adults and children were at the acceptable level under residential (1.62E−05 and 6.39E−05) and recreational scenario (5.41E−06 and 2.46E−05), respectively, as well as for adults in agricultural scenario (1.45E−05). The total non-carcinogenic risk values for both adults and children under residential scenario (1.63E−01 and 4.55E−01, respectively), under recreational scenario (2.88E−01 and 6.69E−01, respectively) and for adults (1.03E−01) under agricultural scenario indicated that adverse health effects were not likely to be observed. Investigated soils were fully suitable for edible plant cultivation.

  • Using human hair and nails as biomarkers to assess exposure of potentially harmful elements to populations living near mine waste dumps 2019-07-17


    Potentially harmful elements (PHEs) manganese (Mn), cobalt (Co), copper (Cu), lead (Pb), nickel (Ni) and zinc (Zn) were measured in human hair/nails, staple crops and drinking water to ascertain the level of exposure to dust transference via wind and rain erosion for members of the Mugala community living near a mine waste dump in the Zambian Copperbelt. The mean PHE concentrations of hair in decreasing order were Zn (137 ± 21 mg/kg), Cu (38 ± 7 mg/kg), Mn (16 ± 2 mg/kg), Pb (4.3 ± 1.9 mg/kg), Ni (1.3 ± 0.2 mg/kg) and Cr (1.2 ± 0.2 mg/kg), Co (0.9 ± 0.2 mg/kg) and Cd (0.30 ± 0.02 mg/kg). Whilst for toenails the decreasing order of mean concentrations was Zn (172 ± 27 mg/kg), Cu (30 ± 5 mg/kg), Mn (12 ± 2 mg/kg), Pb (4.8 ± 0.5 mg/kg), Ni (1.7 ± 0.14 mg/kg) and Co (1.0 ± 0.02 mg/kg), Cr (0.6 ± 0.1 mg/kg) and Cd (0.1 ± 0.002 mg/kg). The concentration of these potentially harmful elements (PHEs) varied greatly among different age groups. The results showed that Mn, Co, Pb, Cd and Zn were above the interval values (Biolab in Nutritional and environmental medicine, Hair Mineral Analysis, London, 2012) at 0.2–2.0 mg/kg for Mn, 0.01–0.20 mg/kg for Co, < 2.00 mg/kg for Pb, < 0.10 mg/kg for Cd and 0.2–2.00 mg/kg for Zn, whilst Ni, Cu and Cr concentrations were within the normal range concentrations of < 1.40 mg/kg, 10–100 mg/kg and 0.1–1.5 mg/kg, respectively. Dietary intake of PHEs was assessed from the ingestion of vegetables grown in Mugala village, with estimated PHE intakes expressed on a daily basis calculated for Mn (255), Pb (48), Ni (149) and Cd (33) µg/kg bw/day. For these metals, DI via vegetables was above the proposed limits of the provisional tolerable daily intakes (PTDIs) (WHO in Evaluation of certain food additive and contaminants, Seventy-third report of the Joint FAO/WHO Expert Committee on Food Additives, 2011) for Mn at 70 µg/kg bw/day, Pb at 3 µg/kg bw/day, Ni and Cd 5 µg/kg bw/day and 1 µg/kg bw/day, respectively. The rest of the PHEs listed were within the PTDIs limits. Therefore, Mugala inhabitants are at imminent health risk due to lead, nickel and cadmium ingestion of vegetables and drinking water at this location.