SEGH Articles

# SEGH 2015: a PhD researchers perspective

15 October 2015
Dan Middleton, a PhD student from the University of Manchester, based at the Centre for Environmental Geochemistry at the British Geological Survey, shares his account of the conference proceedings.

June saw the 31st International Conference of the Society for Environmental Geochemistry and hosted by the State Geological Institute of Dionýz Štúr (SGIDŠ) in Bratislava, Slovak Republic. Dan Middleton, a BUFI funded PhD student from the University of Manchester, based at the Centre for Environmental Geochemistry at the British Geological Survey, shares his account of the conference proceedings.

The coming together of our scientific community to disseminate and share recent and ongoing research findings is, in my opinion, a vital aspect of the development process of our rapidly growing field. Our community in particular is a relatively tight-knit group compared to the core scientific disciplines and one which crosses many boundaries, making networking opportunities such as SEGH 2015 essential for sharing expertise and gaining contacts across broad skill sets. A small community it may be, but nevertheless, more than 80 delegates from 24 countries covering 4 continents descended on the Holiday Inn, Bratislava to fuel a fruitful showcase of projects covering  themes of analytical chemistry, geochemistry, environmental epidemiology and medical geology to name but a few.

Of particular interest to me were the health related topics, as they bridge the gap between measurements of inorganic and organic substances in our environment and how they affect our well-being, both detrimentally and beneficially. This matter was addressed early on by Prof. Stanislav Rapant, hosting the event, in his opening presentation. Using a geochemical baseline survey spanning the whole of the Slovak Republic, Prof Rapant and colleagues from SGIDŠ were able to link concentrations of calcium (Ca) and magnesium (Mg) in drinking water to health statistics of cardiovascular disease (CVD), finding an inverse correlation between exposure and outcome. This research highlighted the first of two take-home messages for me personally – drinking water chemistry is often studied in the light of excess concentrations of chemical elements (I myself gave a presentation on arsenic (As) in UK private water supplies) but of equal importance to human health is ensuring a sufficient supply of the elements that underpin key physiological mechanisms, a point reinforced by Dr Alex Stewart in his talk on the negative health implications of iodine (I) deficiency.

BGS’s very own Dr Mark Cave was in attendance and presented a keynote lecture on findings from a recent project examining the links between London’s soil geochemistry and health related deprivation indices. Mark found that the while unemployment showed the strongest link with detrimental health outcomes, tin (Sn) in soils showed a curious relationship out of the elements studied. This relationship requires further investigation as the causal link between the two variables in not established, however the study demonstrates the power of computer based statistical modelling, in this case the random forest method, in unlocking the secrets of large multivariate datasets.

Another standout talk was that of Dr Munir Zia from the Fauji Fertilizer Company in Pakistan, who presented collaborate research with BGS on potentially harmful elements and dietary minerals in vegetable crops grown in wastewater irrigated soils. Dr Zia used a multitude of techniques to measure both the total and bioaccessible concentrations of analytes in soil and vegetable samples as well as estimating daily intake rates based on literature derived figures and comparing with existing guidance values. For me this highlighted the importance of using an interdisciplinary approach to research problems such as these and addressing the question from a number of angles. This allows us to not only quantify the chemical composition of the media we study, but begin to explore the potential impacts that these compositions may or may not have on our health.

This leads me to the second take-home message of the conference. As geochemists, analytical chemists and environmental scientists, we have an abundance of instrumental techniques at our disposal that enable us to generate quantitative chemical data across a diverse range of samples. What many of us lack in our armoury is the medical and epidemiological expertise to compliment such findings. Environmental Geochemistry and Health is an ever important field and as researchers we need to make sure that both sides of the discipline are maintained. This will be achieved through the coming together of those from both the physical and medical sciences and in particular through the continued engagement of the latter. Furthermore, the personal development of skills outside our respective backgrounds will also aid in forming an adhesive bond between the two factions and promote research that gets closer to answering the question of how our environment impacts our health.

Overall, another worthwhile and insightful meeting that demonstrated the ongoing efforts of our community to engage in diverse research problems using techniques, both analytically and statistically, that are cutting-edge and at the forefront of our field. A big thank you to organisers and delegates alike for making SEGH 2015 a memorable event as we look towards Brussels 2016.

Daniel Middleton, PhD Researcher

University of Manchester and British Geological Survey

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## Science in theNews

Latest on-line papers from the SEGH journal: Environmental Geochemistry and Health

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### Abstract

Fine particulate matter (PM2.5) levels, carbon dioxide (CO2) levels and particle-number concentrations (PNC) were monitored in train carriages on seven routes of the mass transit railway in Hong Kong between March and May 2014, using real-time monitoring instruments. The 8-h average PM2.5 levels in carriages on the seven routes ranged from 24.1 to 49.8 µg/m3, higher than levels in Finland and similar to those in New York, and in most cases exceeding the standard set by the World Health Organisation (25 µg/m3). The CO2 concentration ranged from 714 to 1801 ppm on four of the routes, generally exceeding indoor air quality guidelines (1000 ppm over 8 h) and reaching levels as high as those in Beijing. PNC ranged from 1506 to 11,570 particles/cm3, lower than readings in Sydney and higher than readings in Taipei. Correlation analysis indicated that the number of passengers in a given carriage did not affect the PM2.5 concentration or PNC in the carriage. However, a significant positive correlation (p < 0.001, R 2 = 0.834) was observed between passenger numbers and CO2 levels, with each passenger contributing approximately 7.7–9.8 ppm of CO2. The real-time measurements of PM2.5 and PNC varied considerably, rising when carriage doors opened on arrival at a station and when passengers inside the carriage were more active. This suggests that air pollutants outside the train and passenger movements may contribute to PM2.5 levels and PNC. Assessment of the risk associated with PM2.5 exposure revealed that children are most severely affected by PM2.5 pollution, followed in order by juveniles, adults and the elderly. In addition, females were found to be more vulnerable to PM2.5 pollution than males (p < 0.001), and different subway lines were associated with different levels of risk.

• Comparison of chemical compositions in air particulate matter during summer and winter in Beijing, China 2017-08-01

### Abstract

The development of industry in Beijing, the capital of China, particularly in last decades, has caused severe environmental pollution including particulate matter (PM), dust–haze, and photochemical smog, which has already caused considerable harm to local ecological environment. Thus, in this study, air particle samples were continuously collected in August and December, 2014. And elements (Si, Al, V, Cr, Mn, Fe, Ni, Cu, Zn, Mo, Cd, Ba, Pb and Ti) and ions ( $${\text{NO}}_{3}^{-}$$ , $${\text{SO}}_{4}^{2-}$$ , F, Cl, Na+, K+, Mg2+, Ca2+ and $${\text{NH}}_{4}^{+}$$ ) were analyzed by inductively coupled plasma mass spectrometer and ion chromatography. According to seasonal changes, discuss the various pollution situations in order to find possible particulate matter sources and then propose appropriate control strategies to local government. The results indicated serious PM and metallic pollution in some sampling days, especially in December. Chemical Mass Balance model revealed central heating activities, road dust and vehicles contribute as main sources, account for 5.84–32.05 % differently to the summer and winter air pollution in 2014.

• Annual ambient atmospheric mercury speciation measurement from Longjing, a rural site in Taiwan 2017-08-01

### Abstract

The main purpose of this study was to monitor ambient air particulates and mercury species [RGM, Hg(p), GEM and total mercury] concentrations and dry depositions over rural area at Longjing in central Taiwan during October 2014 to September 2015. In addition, passive air sampler and knife-edge surrogate surface samplers were used to collect the ambient air mercury species concentrations and dry depositions, respectively, in this study. Moreover, direct mercury analyzer was directly used to detect the mercury Hg(p) and RGM concentrations. The result indicated that: (1) The average highest RGM, Hg(p), GEM and total mercury concentrations, and dry depositions were observed in January, prevailing dust storm occurred in winter season was the possible major reason responsible for the above findings. (2) The highest average RGM, Hg(p), GEM and total mercury concentrations, dry depositions and velocities were occurred in winter. This is because that China is the largest atmospheric mercury (Hg) emitter in the world. Its Hg emissions and environmental impacts need to be evaluated. (3) The results indicated that the total mercury ratios of Kaohsiung to that of this study were 5.61. This is because that Kaohsiung has the largest industry density (~60 %) in Taiwan. (4) the USA showed average lower mercury species concentrations when compared to those of the other world countries. The average ratios of China/USA values were 89, 76 and 160 for total mercury, RGM and Hg(p), respectively, during the years of 2000–2012.