Society for Environmental Geochemistry and Health

Environ Geochem Health. 2013 May 23;
Song Y, Liu H

In this study, Yitong River, which is located in Changchun, a representative city in northeastern China, was selected as the research area. Using position monitoring and field measurements, we quantitatively investigated the migration path and flux of nitrogen in a gully region in Changchun City undergoing rapid urbanization. The results showed that at the Yitong River subwatershed, the total nitrogen input flux was 188 kg/hm(2), the degree of which can be ranked in descending order as fertilizer input > biological immobilization > feed > atmospheric deposition. The total nitrogen output flux was 102.5 kg/hm(2), ranked in descending degree as products > waste output > denitrification > surface runoff. The net nitrogen storage was 85.5 kg/hm(2). The migration path and flux of nitrogen were markedly impacted by human activities, showing an imbalance between input and output, as well as a tendency toward nitrogen accumulation and pollution. The nitrogen budget for the Yitong River subwatershed suggested that more than 50 % of the net anthropogenic nitrogen input was lost to the environment, and about 14.5 % was discharged in rivers, indicating that agricultural and human activities in the basin substantially impact the river water quality and thus alter the nitrogen environmental geochemistry. Reducing the application and improving the efficiency of nitrogenous fertilizer use as well as reclaiming human life waste are efficient approaches to decreasing the nitrogen input flux and environmental accumulation and to promoting the balance between nitrogen input and output. These practices are also effective approaches to reducing non-point source pollution.

Environ Geochem Health. 2013 May 12;
Gray JE, Rimondi V, Costagliola P, Vaselli O, Lattanzi P

Stream sediment, stream water, and fish were collected from a broad region to evaluate downstream transport and dispersion of mercury (Hg) from inactive mines in the Monte Amiata Hg District (MAMD), Tuscany, Italy. Stream sediment samples ranged in Hg concentration from 20 to 1,900 ng/g, and only 5 of the 17 collected samples exceeded the probable effect concentration for Hg of 1,060 ng/g, above which harmful effects are likely to be observed in sediment-dwelling organisms. Concentrations of methyl-Hg in Tiber River sediment varied from 0.12 to 0.52 ng/g, and although there is no established guideline for sediment methyl-Hg, these concentrations exceeded methyl-Hg in a regional baseline site (<0.02 ng/g). Concentrations of Hg in stream water varied from 1.2 to 320 ng/L, all of which were below the 1,000 ng/L Italian drinking water Hg guideline and the 770 ng/L U.S. Environmental Protection Agency (USEPA) guideline recommended to protect against chronic effects to aquatic wildlife. Methyl-Hg concentrations in stream water varied from <0.02 to 0.53 ng/L and were generally elevated compared to the baseline site (<0.02 ng/L). All stream water samples contained concentrations of As (<1.0-6.2 μg/L) and Sb (<0.20-0.37 μg/L) below international drinking water guidelines to protect human health (10 μg/L for As and 20 μg/L for Sb) and for protection against chronic effects to aquatic wildlife (150 μg/L for As and 5.6 μg/L for Sb). Concentrations of Hg in freshwater fish muscle ranged from 0.052-0.56 μg/g (wet weight), mean of 0.17 μg/g, but only 17 % (9 of 54) exceeded the 0.30 μg/g (wet weight) USEPA fish muscle guideline recommended to protect human health. Concentrations of Hg in freshwater fish in this region generally decreased with increasing distance from the MAMD, where fish with the highest Hg concentrations were collected more proximal to the MAMD, whereas all fish collected most distal from Hg mines contained Hg below the 0.30 μg/g fish muscle guideline. Data in this study indicate some conversion of inorganic Hg to methyl-Hg and uptake of Hg in fish on the Paglia River, but less methylation of Hg and Hg uptake by freshwater fish in the larger Tiber River.

Environ Geochem Health. 2013 May 5;
Fujimori T, Takigami H

We studied distribution of heavy metals [lead (Pb), copper (Cu) and zinc (Zn)] in surface soil at an electronic-waste (e-waste) recycling workshop near Metro Manila in the Philippines to evaluate the pollution size (spot size, small area or the entire workshop), as well as to assess heavy metal transport into the surrounding soil environment. On-site length-of-stride-scale (~70 cm) measurements were performed at each surface soil point using field-portable X-ray fluorescence (FP-XRF). The surface soil at the e-waste recycling workshop was polluted with Cu, Zn and Pb, which were distributed discretely in surface soil. The site was divided into five areas based on the distance from an entrance gate (y-axis) of the e-waste recycling workshop. The three heavy metals showed similar concentration gradients in the y-axis direction. Zn, Pb and Cu concentrations were estimated to decrease to half of their maximum concentrations at ~3, 7 and 7 m from the pollution spot, respectively, inside the informal e-waste recycling workshop. Distance from an entrance may play an important role in heavy metal transport at the soil surface. Using on-site FP-XRF, we evaluated the metal ratio to characterise pollution features of the solid surface. Variability analysis of heavy metals revealed vanishing surficial autocorrelation over metre ranges. Also, the possibility of concentration prediction at unmeasured points using geostatistical kriging was evaluated, and heavy metals had a relative "small" pollution scales and remained inside the original workshop compared with toxic organohalogen compounds. Thus, exposure to heavy metals may directly influence the health of e-waste workers at the original site rather than the surrounding habitat and environmental media.